Synthesis of chitosan based new material for recovery of Pt (IV)

Authors

  • Enkhtuya Majigsuren 96678609
  • Ulziidelger Byambasuren Department of Chemical Engineering, School of Applied Sciences, Mongolian University of Science and Technology, Ulaanbaatar, Mongolia
  • Gachimeg Yunden Department of Chemical Engineering, School of Applied Sciences, Mongolian University of Science and Technology, Ulaanbaatar, Mongolia https://orcid.org/0000-0003-4740-2018
  • Nasanjargal Shirendev Department of Chemical Engineering, School of Applied Sciences, Mongolian University of Science and Technology, Ulaanbaatar, Mongolia
  • Chuluuntsetseg Tserendorj Department of Chemical Engineering, School of Applied Sciences, Mongolian University of Science and Technology, Ulaanbaatar, Mongolia
  • Munkhpurev Bat-Amgalan Department of Chemical Engineering, School of Applied Sciences, Mongolian University of Science and Technology, Ulaanbaatar, Mongolia
  • Naoki Kano Department of Chemistry and Chemical Engineering, Faculty of Engineering, Niigata University, Japan

DOI:

https://doi.org/10.5564/jasea.v4i1.3159

Keywords:

adsorption kinetics, adsorption thermodynamics, platinum recovery

Abstract

In this study a new type of adsorbent bead precursor was reached using chitosan and pretreated clay. The pretreated clay was produced from the clay of the "Tsogt-Ovoo" deposit in the Umnugovi province of Mongolia. It was produced by acid and heat treatment to remove its mechanical impurities. The mixtures of chitosan and pretreated clay were taken with various ratios (8:1, 8:2, and 8:3) for chemical processing to obtain a chitosan-based adsorbent bead for recovery of  (Pt(IV)) from aqueous solution. It was examined that the adsorption capacity of the adsorbent bead when the chitosan and pretreated clay mass ratio 8:2 was the highest for platinum ion (Pt (IV)). The adsorption properties of Pt (IV) were studied depending on the solution pH, contacting time, temperature, initial concentration of platinum ion solution, and amount of adsorbent material. The adsorption efficiency was the highest (93.29%) when the initial concentration of the platinum ion was 50 mg/l at the following condition; pH=3, temperature 250C, time 3 hours, and the amount of the adsorbent material 0.1 g. It represents that the chitosan clay bead can be applied for the recovery of platinum (Pt (IV)) from aqueous solution. 

Abstract
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Author Biography

Enkhtuya Majigsuren, 96678609

department of chemical enginering training master

References

T. Kang, Y. Park, J.C. Park, Y.S. Cho, and J. Yi, Functionalized mesoporous adsorbents for Pt (II) and Pd(I) adsorption from dilute aqueous solution, Stud. Surf. Sci. Catal. 146 (2003), pp. 527-530. https://doi.org/10.1016/S0167-2991(03)80437-8

E. Renbutsu, S. Okabe, Y. Omura, F. Nakatsubo, S. Minami, H. Saimoto, and Y. Shigemasa, Synthesis of UV-curable chitosan derivatives and palladium (II) adsorption behavior on their UV-exposed films, Carbohydr. Polym. 69 (2007), pp. 697-706. https://doi.org/10.1016/j.carbpol.2007.02.018

H.T. Nguyen, W. Masayuki, and K. Takaumi, Solvent extraction of palladium (II) with various ketones from nitric acid medium, Solvent Extr. Ion. Exch, 25 (2007), pp. 407-416. https://doi.org/10.1080/07366290701285538

B. Godlewska-Żylkiewicz, B. Leśniewska, U. Gąsiewska and A. Hulanicki, Ion exchange preconcentration and separation of trace amounts of platinum and palladium, Anal. Lett. 33 (2000), pp. 2805-2820. https://doi.org/10.1080/00032710008543224

M. Ruiz, A.M. Sastre, E. Guibal, Palladium sorption on glutaraldehyde crosslinked chitosan, React. Funct. Polym. 45 (2000), pp. 155-173. https://doi.org/10.1016/S1381-5148(00)00019-5

E. Guibal, Interactions of metal ions with chitosan-based sorbents: a review, Sep. Purif. Technol. 38 (2004), pp. 43-74. https://doi.org/10.1016/j.seppur.2003.10.004

D. Sicupira, K. Campos, T. Vincent, V. Leao and E. Guibal, Palladium and platinum sorption using chitosan-based hydrogels, Adsorption (2010), pp. 127–139. https://doi.org/10.1007/s10450-010-9210-9.

M. Jiang, X. Jin, X. Lu and Z. Chen, Adsorption of Pb(II), Cd(II), Ni(I) and Cu(II) onto natural kaolinite clay, School of Chemistry and Materials Science, Fujian Normal University, Fuzhou, 350007, China, pp. 33-39. https://doi.org/10.1016/j.desal.2009.11.005

Subari and Tatang wahyudi, Improving tapin kaolin quality for white ware ceramic, Indonesian mining journal Vol. 17, No. 2, June 2014, pp. 87-97.

E. Igberase and P. Osifo, Equilibrium, kinetic, thermodynamic and desorption studies of cadmium and lead by polyaniline grafted cross-linked chitosan beads from aqueous solution, Journal of Industrial and Engineering Volume 26, 25 June 2015, pp. 340-347. https://doi.org/10.1016/j.jiec.2014.12.007

D. Lin, S. Dezhi, and L. Yangqing, Removal of Cu(II) and Cd(II) From Aqueous Solutions by Polyaniline on Sawdust, Sep. Sci. Technol. 46 (2011). pp. 321-329. https://doi.org/10.1080/01496395.2010.504201

M. Chiban, G. Carja, G. Lehutu, F. Sinan and Arab. J, Equilibrium and thermodynamic studies for the removal of As (V) ions from aqueous solution using dried plants as adsorbents, Chem. 33 (2012), pp. 12-20. https://doi.org/10.1016/j.arabjc.2011.10.002

Ts, Girma Asere, S, Mincke, K, Folens, F, Vanden Bussche, L, Lapeire, K, Verbeken, P, Van DeVoort, A, Tessema, G, Du Laing, and V. Stevens, Dialdehyde carboxymethyl cellulose cross-linked chitosan for the recovery of palladium and platinum from aqueous solution, Volume 141, August 2019, pp. 145-154. https://doi.org/10.1016/j.reactfunctpolym.2019.05.008

L. Jinhui, J. Liu, and Zh. Liu, Adsorption of platinum (IV) and palladium (II) from aqueous solution by thiourea-modified chitosan microspheres, 15 December 2009, pp. 439-446. https://doi.org/10.1016/j.jhazmat.2009.07.030

S. Aktas and M.H. Morcali, Platinum recovery from dilute platinum solutions using activated carbon, November 2011, pp. 2554-2558. https://doi.org/10.1016/S1003-6326(11)61091-1

Sh, Sharma , A. Santhana Krishna Kumar and N. Rajesh, A perspective on diverse adsorbent materials to recover precious palladium and the way forward , 2017, 7, pp. 52133-52142. https://doi.org/10.1039/C7RA10153H

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Published

2023-12-28

How to Cite

[1]
E. Majigsuren, “Synthesis of chitosan based new material for recovery of Pt (IV)”, J. appl. sci. eng., A, vol. 4, no. 1, pp. 16–26, Dec. 2023.

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