Effect of various transition metal ions on mordanting stage of yak wool bleaching process
DOI:
https://doi.org/10.5564/mjc.v23i49.2138Keywords:
yak wool, transition metal ions, mordanting, bleachingAbstract
Yak wool is a smooth, warm, and durable natural protein-structured fiber that could compete with cashmere and other high-end protein-structured fibers on the market. However, it suffers from drawing consumers’ attention due to the lack of color due to the shortfall of the yak wool bleaching technology. Herein, we studied the applicability of various transition metals, i.e., copper (II), cobalt (II), iron (II), and nickel (II) salts, as a mordanting reagent based on their effect on the hydrogen peroxide decomposition reaction and the morphological and mechanical properties of the bleached yak wool with the presence of these transition metal. Our study suggested that the iron (II) ion was the most efficient reagent for the mordant bleaching since it provided less fiber damage, relatively high strength, and elongation to the bleached yak wool with good whiteness, while the Cu (II) was the least favorable agent for the yak wool bleaching process.
Downloads
226
References
Stoves J.L. (1976) Principles of fur dyeing. J. Soc. Dye. Colour., 92, 213-226. https://doi.org/10.1111/j.1478-4408.1976.tb03288.x
Bereck A. (1994) Bleaching of pigmented speciality animal fibres and wool. Rev. Prog. Color. Relat. Top., 24, 17-25. https://doi.org/10.1111/j.1478-4408.1994.tb03764.x
Roy A.N., Samanta K.K., and Patra K. (2019) Physico-chemical properties of black yak fibre and its modification for blending with jute fibre. J. Nat. Fibers., 16, 225-236. https://doi.org/10.1080/15440478.2017.1414652
Liu C., Xie C., and Liu X. (2018) Properties of yak wool in comparison to cashmere and camel hairs. J. Nat. Fibers., 15, 162-173. https://doi.org/10.1080/15440478.2016.1212762
Mortazavi S.M., Safi S., Moghadam M.K., and Zamani M. (2014) Bleaching of black pigmented karakul wool fibers using copper sulfate as catalyst. Fibers Polym., 15, 2297-2306. https://doi.org/10.1007/s12221-014-2297-y
Arifoglu M., Marmer W.N. (1990) Sequential oxidative and reductive bleaching of stained and pigmented wool in a single bath. Fibers Polym., 60, 549-554. https://doi.org/10.1177/004051759006000909
Hall J.A., Vuocolo L.D., Suckling I.D., Horwitz C.P., Allison R.W., et al. (1999) Development of the PFe Process: A new catalysed hydrogen peroxide bleaching process. In 53rd Appita Annual General Conference, 2, 455-461.
Cardamone J. and Marmer W. (1995) The whitening of textiles. In: Carr. C.M. (eds). Chemistry of the Textiles Industry, Springer, 46-101. https://doi.org/10.1007/978-94-011-0595-8_2
Laxer G. and Whewell C.S. (1953) Adsorption of metal ions by naturally pigmented keratin fibres. J. Soc. Dye. Colour., 69, 83-84. https://doi.org/10.1111/j.1478-4408.1953.tb02817.x
Khishigsuren A., Nakajima M., and Takahashi M. (2001) Effects of ferrous mordanting on bleaching of camel hair. Text. Res. J., 71, 487-494. https://doi.org/10.1177/004051750107100604
Oh K., Park M., and Kang T. (1997) Effect of mordant bleaching on the optical and mechanical properties of black human hair. J. Soc. Dye. Colour., 113, 243-249. https://doi.org/10.1111/j.1478-4408.1997.tb01908.x
Liu X., Hurren C.J., and Wang X. (2003) Comparative analysis of two selective bleaching methods on alpaca fibers. Fibers Polym., 4, 124-128. https://doi.org/10.1007/BF02875459
Hodes J., Sielaff P., Metz H., Kessler-Becker D., Gassenmeier T., et al. (2018) The role of chelating agents and amino acids in preventing free radical formation in bleaching systems. Free Radic. Biol. Med., 129, 194-201. https://doi.org/10.1016/j.freeradbiomed.2018.09.023
Korytowski W. and Sarna T. (1990) Bleaching of melanin pigments. Role of copper ions and hydrogen peroxide in autooxidation and photooxidation of synthetic dopa-melanin. J. Biol. Chem., 265, 12410-12416. https://doi.org/10.1016/S0021-9258(19)38362-0
Smith R.A.W., Garrett B., Naqvi K.R., Fülöp S.P., Godfrey S.P., et al. (2017) Mechanistic insights into the bleaching of melanin by alkaline hydrogen peroxide. Free Radic. Biol. Med., 108, 110-117. https://doi.org/10.1016/j.freeradbiomed.2017.03.014
Moody V. and Needles H.L. (2004) Tufted carpet: Textile fibers, dyes, finishes and processes, William Andrew.
Yan K., Höcker H., and Schäfer K. (2000) Handle of bleached knitted fabric made from fine yak hair. Text. Res. J., 70, 734-738. https://doi.org/10.1177/00405175000700081
Arildii D., Davaasambuu S., Bazarvaani A., and Javzandulam D. (2020) Optimization of mordant bleaching of yak wool with hydrogen peroxide at low temperature. J. Nat. Fibers, 19, 2527-2538. https://doi.org/10.1080/15440478.2020.1819512
Knott J. (1990) Fine animal fibres and their depigmentation process, Universidade do Minho.
Silberberg M.S. (2013) Principles of general chemistry. McGraw-Hill, NY.
Brooks R.E. and Moore S.B. (2000) Alkaline hydrogen peroxide bleaching of cellulose. Cellulose, 7, 263-286. https://doi.org/10.1023/A:1009273701191
Kissa E., Dohner J.M., Gibson W.R., and Strickman D. (1991) Kinetics of staining and bleaching. JAOCS, 68, 532-538. https://doi.org/10.1007/BF02663830
Lide D.R. (2004) CRC handbook of chemistry and physics. Vol. 85. CRC press.
Pearson R.G. (1968) Hard and soft acids and bases, HSAB, part 1: Fundamental principles. J. Chem. Educ., 45, 581. https://doi.org/10.1021/ed045p581
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2022 Dashjargal Arildii, Otgontsetseg Ranaajav, Odonchimeg Genenbat, Amarzaya Bazarvaani, Sarangerel Davaasambuu
This work is licensed under a Creative Commons Attribution 4.0 International License.
Copyright on any research article in the Mongolian Journal of Chemistry is retained by the author(s).
The authors grant the Mongolian Journal of Chemistry a license to publish the article and identify itself as the original publisher.
Articles in the Mongolian Journal of Chemistry are Open Access articles published under a Creative Commons Attribution 4.0 International License CC BY.
This license permits use, distribution and reproduction in any medium, provided the original work is properly cited.