Treatment of copper-containing leaching residue by sulfation roasting followed by acid/water leaching

Authors

DOI:

https://doi.org/10.5564/mjc.v24i50.1310

Keywords:

copper technogen concentrate, thermal analysis, air- and oxygen roasting, acid/water leaching

Abstract

This research investigates the extraction of copper from copper-containing leaching residue, which includes 33.45% of copper, 14.14% of iron, 23.87% of sulfur and trace amounts of silver and other elements. Roasting the copper-containing residue under air and oxygen flow convert sulfides into sulfate, followed by water and acid leaching to extract copper. The process parameters, including leaching temperature, sulfuric acid concentration, leaching time, solid-to liquid ratio, and agitation speed, were optimized for both water and acid leaching methods. Results showed that the maximum copper dissolution efficiency was 93.12% with water leaching, and 97.16% with acid leaching. Chemical analysis revealed that the water and acid leaching residue contained 48.13% and 31.64% of iron, respectively. This study provides valuable insights into the process optimization for copper extraction from copper-containing leaching residue, which can inform the development of more efficient and sustainable methods for metal recovery.

Downloads

Download data is not yet available.
Abstract
366
PDF
418

References

Javkhlan O., Munkhtsengel B. (2021) Silver Deposits. In: Gerel O., Pirajno F., Batkhishig B., Dostal J. (eds) Mineral Resources of Mongolia. Modern Approaches in Solid Earth Sciences, 19, Springer, Singapore. https://doi.org/10.1007/978-981-15-5943-3_9

Ochirbat P. (1999) Strategy and ecology of noble minerals complex development. UB, 347 -374

Nyamdelger S., Burmaa G., Narangarav T-U. Ariunaa G. (2013) Dissolution behaviour of freibergite-tetrahedrite concentrate in acidic dichromate solution. Mong. J. Chem, 14(40), 36-40. https://doi.org/10.5564/mjc.v14i0.196

Schlesinger M.E., King M.J., Davenport W.G. (2011) Extractive metallurgy of copper. Elsevier, UK. ISBN 978-0-08-096789-9

Mitovski A., Strbac N., Mihajlovic I., Sokic M., Stojanovic J. (2014) Thermodynamic and kinetic analysis of the polymetallic copper concentrate oxidation process. J. Therm. Anal. Calorim., 118, 1277-1285. https://doi.org/10.1007/s10973-014-3838-8

Aghazadeh S., Abdollahi H., Gharabaghi M., Mirmohammadi M. (2021) Selective leaching of antimony from tetrahedrite rich concentrate using alkaline sulfide solution with experimental design: Optimization and kinetic studies. J. Taivan Inst. Chem. Eng., 119, 298-312. https://doi.org/10.1016/j.jtice.2021.01.021

Balaz P., Sekula F., Jakabsky S., Kamme, l.R. (1995) Application of attrition grinding in alkaline leaching of tetrahedrite. Miner. Eng., 8(11), 1299-1308. https://doi.org/10.1016/0892-6875(95)00097-A

Ukasik M., Havlik T. (2005) Effect of selected parameters on tetrahedrite leaching by ozone. Hydrometallurgy, 77, 139-45. https://doi.org/10.1016/j.hydromet.2004.10.017

Dimitrijevic M. D., Urosevic D.M., Jankovic Z.D., Milic S. M. (2016) Recovery of copper from smelting slag by sulphation roasting and water leaching. Physicoche. Probl. Miner. Process, 52(1), 409-421. https://doi.org/10.5277/ppmp160134

Lucheva B., Iliev P., Kolev D. (2017) Hydro-pyrometallurgical treatment of copper convertor flue dust. J. Chem. Tech. Metall., 52(2), 320-325

Gorai B., Jana R.K., Kha, Z.H. (2002) Electrorefining electrolyte from copper plant dust. Mater. Trans., 43(3), 532–536. https://doi.org/10.2320/matertrans.43.532

Zhao Y., Hou Y., Cui Y., Liang H., Li L. (2015) Recovery of copper from copper sulfide concentrate by sulfation roasting. Inter. J. Nonferrous Met., 4, 9-13. https://doi.org/10.4236/ijnm.2015.42002

Priya J., Randhawa N.S., Hait J., Bordoloi N., Patel J.N. (2020) High purity copper recycled from smelter dust by sulfation roasting, water leaching and electrorefining. Environ. Chem. Lett., 18, 2133-2139. https://doi.org/10.1007/s10311-020-01047-0

Shamsuddin M. (2021) Roasting of Sulfide Minerals. In: Physical Chemistry of Metallurgical Processes. Second Edition. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-58069-8_2

Ariunaa G., Burmaa G., Nyamdelger S., Altansukh B., Nazgul M., Narangarav T-U. (2021) Some results of studies on leaching of toxic elements in Asgat polymetallic concentrate. Bulletin of the Institute of Chemistry and Chemical Technology, 4(9), 17-25 https://doi.org/10.5564/bicct.v4i9.1814

Samuel A.A., Samuelsson C., Sandström A. (2010) Dissolution kinetics of tetrahedrite mineral in alkaline sulphidemedia. Hydrometallurgy, 103, 167-172. https://doi.org/10.1016/j.hydromet.2010.03.014

Prasad S., Pandey B.D. (1999) Thermoanalytical Studies on Copper-Iron Sulphides. J. Therm. Anal. Calorim., 58, 625-637. https://doi.org/10.1023/A:1010108729034

Nyamdelger Sh., Narangarav T-U., Nemekhbayar D., Sarantsetseg P., Surenjav E. et. al., (2022) Copper extraction from the sulphation roasted copper technogen concentrate. Bulletin of the Institute of Chemistry and Chemical Technology, 10, 1-9. https://doi.org/10.5564/bicct.v10i10.1483

Downloads

Published

2023-06-19

How to Cite

Shirchinnamjil, N., Tumen-Ulzii, N., Davaadorj, N., Byambasuren, K., Purevsuren, S., Erdenebat, U., & Surenjav, E. (2023). Treatment of copper-containing leaching residue by sulfation roasting followed by acid/water leaching. Mongolian Journal of Chemistry, 24(50), 18–26. https://doi.org/10.5564/mjc.v24i50.1310

Issue

Section

Articles